个人信息
董喜燕 博士
出生日期: 1978-07-20
出生地: 河南焦作
国籍: 中国
语言: 中文, 英语
E-mail: dongxiyan0720@hpu.edu.cn
研究方向：
金属团簇
发光材料
晶态材料
教育/访学经历：
2023.7-2024.7 加拿大，阿尔伯塔大学（ University of Alberta）, 访问学者
2017.6-2018.6 香港中文大学 访问学者
2011.9-2015.6 郑州大学，化学与分子工程学院，无机化学，博士，
2002.9-2005.7河南大学，教育部特种功能材料重点实验室，凝聚态物理，硕士
1996.9-2000.7 河南大学，化学化工学院，化学工程，学士
工作经历：
2024 – 至今 教授/博导，河南理工大学
2018 – 2023 副教授/博导，河南理工大学
2005 – 2017: 讲师/硕导，河南理工大学
主持科研项目：
1. 国家自然科学基金委，区域创新发展联合基金重点支持项目，“壳层调控币金属团簇的光学性质研究”，批准号：U21A20277， 直接研究经费：260万元， 2022.01 - 2025.12，主持
2. 国家自然科学基金委，国家自然基金面上项目，“限域效应调控银团簇室温发光研究”， 批准号：21975065， 直接研究经费：66 万， 2020/01-2023/12，主持
3. 国家自然科学基金委，国家自然基金青年科学基金项目，“由金属有机框架和聚合物电解质制备复合质子传导膜及其结构和性能研究”、批准号：21501046、 直接研究经费：20 万， 2016/01-2018/12，主持
4. 河南省科学技术厅，河南省杰出青年科学基金项目，“高效发光金属团簇超分子组装体系”，批准号：232300421022、 50万，2023.1-2025.12，主持
5. 河南省人力资源和社会保障厅，河南省留学人员科研择优项目，“改善银团簇室温发光性能的研究”，5 万，2021-2022，主持
学术活动：
1. The 6th International Symposium on Monolayer Protected Clusters (2019)
2. 9th Chinese Coordination Chemistry Conference, invited talk (2022)
中国化学会第九届全国配位化学会议，邀请报告，2022 年 8 月
3. 第四届团簇科学与原子制造研讨会，邀请报告，2023 年 4 月
4. 新兴功能材料与器件研讨会，邀请报告，2023年12月
获得的荣誉和奖励：
1. 河南省人民政府，河南省自然科学一等奖，“银硫团簇材料定向制备与功能化”, 第二完成人，证书号：2023-Z-001-R02/08，2023年12月15日
2. 河南省人民政府，河南省自然科学一等奖，“响应型金属有机框架材料”，第二完成人，证书号：2019-Z-002-R02/06，2020年1月16日
3. 2020 年度河南省教育厅科技成果奖，一等奖，银团簇基功能材料，第二完成人， 豫教〔2020〕8249 号
4. 河南省教育厅科技成果奖，一等奖“刺激响应型晶态智能材料” 2018年，第四名
发明专利：
1. 发明专利，“一种定向识别二氯甲烷、三氯甲烷、四氯甲烷的荧光变色材料及其制备方法”, ZL 201810187398.2，授权公告日：2020.01.21
2. 发明专利，“一种巯基银簇配位聚合物在氧气检测中的应用”, ZL 201611198810.8, ，授权公告日：2019.05.17
3. 发明专利，“一种Cr基金属-有机框架材料及其制备方法”，ZL 201911186742.7，授权公告日：2021.08.24
4. 发明专利，“一种高量子产率的手性MOF-染料复合材料及其制备方法和应用”，ZL 202010675977.9，授权公告日：2021.12.31
5. 发明专利，“一种手性发光金银掺杂纳米簇材料及其合成方法和应用”，ZL 202211240798.8，授权公告日：2023.08.01
6. 发明专利，“氮磷共掺杂多孔碳包覆磷化亚铜复合型催化剂及其制备方法” ZL 2017 1 0947923.1，授权公告日：2020.01.21
代表性论文：
1. Si Li, Na-Na Li, Xi-Yan Dong,* Shuang-Quan Zang,* and Thomas C. W. Mak, “Chemical Flexibility of Atomically Precise Metal Clusters”, Chem. Rev. 2024, 124, 7262-7378, DOI:
2. Jia-Hong Huang, Ya-Jie Liu, Yubing Si, Yao Cui, Xi-Yan Dong,* and Shuang-Quan Zang, “Carborane-Cluster-Wrapped Copper Cluster with Cyclodextrin-like Cavities for Chiral Recognition”, J. Am. Chem. Soc. 2024, 146, 16729-16736,
3. Tian-Li Pu, Xu-Yang Wang, Zhi-Bing Sun, Xi-Yan Dong,* Qian-You Wang,* and Shuang-Quan Zang*, “Introducing Carborane Clusters into Crystalline Frameworks via Thiol-Yne Click Chemistry for Energetic Materials”, Angew. Chem. Int. Ed. 2024, e202402363
4. Ren Chen, Xiao-Hong Ma, Peng Luo, Chun-Hua Gong, Jun-Jun Sun, Yu-Bing Si, Xi-Yan Dong*, Fangfang Pan* and Shuang-Quan Zang*, “Atomically Precise Ternary Cluster: Polyoxometalate Cluster Sandwiched by Gold Clusters Protected by N-Heterocyclic Carbenes”, Angew. Chem. Int. Ed. 2024, DOI: 10.1002/anie.202408310
5. Jin-Sen Yang, Yu-Jing Zhao, Xin-Mao Li, Xi-Yan Dong*, Yu-Bing Si, Lu-Yao Xiao, Jia-Hua Hu*, Zhihao Yu*, and Shuang-Quan Zang*, “Staggered Assembly of a Dimeric Au13 Cluster:Impacts on Coupling of Geometric Isomerism”, Angew. Chem. Int. Ed. 2024, e202318030.
6. Chong Zhang, Shan Guan, Hai-Yang Li*, Xi-Yan Dong*, Shuang-Quan Zang*, “Metal Clusters Confined in Chiral Zeolitic Imidazolate Framework for Circularly Polarized-Luminescence Inks.”, Nano Lett. 2024, 24, 2048–2056.
7. Zhen Ren, Jun-Jun Sun, Long Xu, Peng Luo, Zi-Wei Ma, Si Li, Yu-Bing Si, Xi-Yan Dong*, Fangfang Pan*, “X-ray-triggered through-space charge transfer and photochromism in silver nanoclusters”, Nanoscale 2024, 16, 2662-2671.
8. Jia-Yin Wang, Jia-Wang Yuan, Xue-Mei Liu, Ying-Jie Liu, Feng Bai, Xi-Yan Dong*, Shuang-Quan Zang*， “Engineering intelligent chiral silver cluster-assembled materials for temperature-triggered dynamic circularly polarized luminescence”, Aggregate 2024; e508.
9. Xiao-Hong Ma, Yubing Si, Jia-Hua Hu, Xi-Yan Dong*, Guohua Xie, Fangfang Pan, Yong-Li We, Shuang-Quan Zang*, Yi Zhao, “High-Efficiency Pure Blue Circularly Polarized Phosphorescence from Chiral N-Heterocyclic-Carbene-Stabilized Copper(I) Clusters”, J. Am. Chem. Soc. 2023, 145, 25874–25886.
10. Jing-Wen Hu, Xue-Yan Wang, Jun Xu, Xi-Yan Dong*, Chong Zhang*, “Hypersensitive ratiometric temperature sensing in a bimetallic lanthanide metal–organic framework”, J. Mater. Chem. C 2023, 11, 14545-14550.
11. Xiao-Hong Ma, Jing Li, Peng Luo, Jia-Hua Hu, Zhen Han, Xi-Yan Dong*, Guohua Xie, Shuang-Quan Zang*, “Carbene-stabilized enantiopure heterometallic clusters featuring EQE of 20.8% in circularly-polarized OLED”, Nat. Commun. 2023, 14, 4121
12. Xue-Jing Zhai, Jia-Hua Hu, Jianxin Guan, Yubing Si, Xi-Yan Dong*, Peng Luo, Fangfang Pan, Zhihao Yu*, Runping Han, Shuang-Quan Zang*, “Luminescence modulation of ultrasmall gold clusters by aromatic ligands”, Nano Research 2023, 16, 11366-11374.
13. Xuan-Hui Zhao, Na-Na Li, Jing Peng, Jun Xu, Peng Luo, Xi-Yan Dong*, Xiaozong Hu*, “Circularly polarized luminescence enlargement from crystals to oriented films of enantiopure 2D hybrid perovskites”, Chem. Commun. 2023,59, 6881-6884.
14. Xuan-Hui Zhao, Na-Na Li, Jun Xu, Xi-Yan Dong*, Si Li*, Shuang-Quan Zang, “Pseudorotaxane Ligand-Induced Formation of Copper(I) Iodide Cluster Based Assembly Materials: From Zero to Three Dimensional”, Chin. J. Chem. 2023, 41, 1943-1949.
15. Jia-Yin Wang, Yubing Si, Xi-Ming Luo, Zhao-Yang Wang, Xi-Yan Dong*, Peng Luo, Chong Zhang, Chunying Duan*, Shuang-Quan Zang*, “Stepwise Amplification of Circularly Polarized Luminescence in Chiral Metal Cluster Ensembles”, Adv. Sci. 2023, 10, 2207660.
16. Yan Jin, Chong Zhang, Xi-Yan Dong*, Shuang-Quan Zang*, and Thomas C. W. Mak, “Shell engineering to achieve modification and assembly of atomically-precise silver clusters”, Chem. Soc. Rev., 2021, 50, 2297-2319.
17. Xi-Ming Luo, Chun-Hua Gong, Fangfang Pan, Yubing Si, Jia-Wang Yuan, Muhammad Asad, Xi-Yan Dong*, Shuang-Quan Zang*, Thomas C. W. Mak “Small symmetry-breaking triggering large chiroptical responses of Ag70 nanoclusters”, Nat. Commun., 2022, 13, 1177.
18. Xi-Yan Dong#, Yubing Si#, Jin-Sen Yang, Chong Zhang, Zhen Han, Peng Luo, Zhao-Yang Wang, Shuang-Quan Zang*, Thomas C. W. Mak, “Ligand engineering to achieve enhanced ratiometric oxygen sensing in a silvercluster-based metal-organic framework”, Nat. Commun. 2020, 11, 3678–3687.
19. Chong Zhang, Zhong-Shan Li, Xi-Yan Dong*, Yun-Yin Niu, and Shuang-Quan Zang*, “Multiple Responsive CPL Switches in an Enantiomeric Pair of Perovskite Confined in Lanthanide MOFs”, Adv. Mater. 2022, 2109496.
20. Yan Jin, Si Li, Zhen Han, Bing-Jie Yan, Hai-Yang Li, Xi-Yan Dong*, Shuang-Quan Zang*, “Cations controlling the chiral assembly of luminescent atomically precise copper(I) clusters”, Angew. Chem. Int. Ed. 2019, 58, 12143–12148.
21. Xi-Yan Dong, Mei Zhang, Ru-Bo Pei, Qian Wang, Dong-Hui Wei, Shuang-Quan Zang*, Yao-Ting Fan, Thomas C. W. Mak, “A crystalline copper(II) coordination polymer for efficient visible-light-driven hydrogen generation”, Angew. Chem. Int. Ed. 2016, 55, 2073–2077.
22. Xi-Yan Dong, Rui Wang, Jia-Bin Li, Shuang-Quan Zang,* Hong-Wei Hou, Thomas C. W. Mak, “Ferroelectric switchable behavior through fast reversible deadsorption of water spirals in a chiral 3D metal−organic framework”, J. Am. Chem. Soc. 2013, 135, 10214−10217.
23. Shan-Shan Liu, Qing-Qing Liu, Sheng-Zheng Huang, Chong Zhang, Xi-Yan Dong*, Shuang-Quan Zang*, “Sulfonic and phosphonic porous solids as proton conductors”, Coordination Chemistry Reviews, 2022 451, 214241.
24. Zhen Han#, Xi-Yan Dong#, Peng Luo, Si Li, Zhao-Yang Wang, Shuang-Quan Zang*, Thomas C. W. Mak, “Ultrastable atomically precise chiral silver clusters with more than 95% quantum efficiency”, Sci. Adv. 2020, 6, eaay0107–0114.
25. Rui Wang#, Xi-Yan Dong#, Jiao Du, Jin-Yan Zhao, Shuang-Quan Zang*, “MOF-derived bifunctional Cu3P nanoparticles coated by a N,P-codoped carbon shell for hydrogen evolution and oxygen reduction”, Adv. Mater. 2018, 30, 1703711−1721.
